Compound removes radioactive material from power plant waste

Layered sulfides bond to strontium 90, other radioactive ions
Strontium 90 is a common radioactive by-product of fission in nuclear power plants. When extracted from the reactor along with other isotopes, a mixture is created made up of the radioactive material and inert ions like sodium and calcium.

Scientists at U.S. Department of Energy’s Argonne National Laboratory and Northwestern University have developed a compound that captures the radioactive ions so they can be siphoned off and separated from inert material.

“The layered sulfides used work quite well,” scientist Mercouri Kanatzidis said. “We even surprised ourselves.”

This mixture is often incredibly acidic or alkaline, making it difficult to find a compound that can survive long enough to extract the strontium and not react with the sodium, which is harmless.

Kanatzidis and colleague Manolis Manos created a synthetic compound made up of sulfides that can survive in the harsh acidic or alkaline climate of the mixture and strip away 99 percent of the strontium 90.

“The material is remarkably simple and can be created in large quantities at a relatively low cost,” Kanatzidis said.

The synthetic compound trades its own potassium ions for strontium and can almost completely replace the radioactive element within a few hours.

The next step is to experiment with the compound’s ability to siphon away other common radioactive elements like cesium and uranium.

Funding for the project was through Northwestern University and the National Science Foundation.

The research has been published in the early online edition of the Proceedings of the National Academy of Sciences.

Argonne National Laboratory brings the world’s brightest scientists and engineers together to find exciting and creative new solutions to pressing national problems in science and technology. The nation’s first national laboratory, Argonne conducts leading-edge basic and applied scientific research in virtually every scientific discipline. Argonne researchers work closely with researchers from hundreds of companies, universities, and federal, state and municipal agencies to help them solve their specific problems, advance America ’s scientific leadership and prepare the nation for a better future. With employees from more than 60 nations, Argonne is managed by UChicago Argonne, LLC for the U.S. Department of Energy’s Office of Science.